The thousand islands is about 140 km from Ottawa. There is a large sign for the exit and you can not miss it. Driving along the parkway is very enjoyable and you could stop over a few sites on your way to your boat tour wharf.
There are a few of options for your boat tour, one-hour or three-hour tours. You can land (you do not have to) on an America castle (Note: you need a visa if you are not a Canadian citizen). There is a cafeteria on boat. Light lunch and coffee et al. are available. You may need one day for the trip. Scenery on both sides of the islands is worth photos taken. Therefore do get your camera ready. Good luck to your tour.