It is very hard to define which physio is good. They should all be similar and the treatment equipment is same. It all depends on what kind of problem to treat.
For shoulder sprain, you should visit the physio as soon as possible if you have insurance coverage. Physio should be very good for this kind of injury.
Been dealing with the sports injuries before, within 48 hours, you should ice the shoulder. After that, you should heat it with a heat bag. Or you can alternate between ice and heat, but always finish with the heat.
But physio will be able to determine your actual injury and suggest some excercises to recover sooner.